5-Bromo-3-ethyl­sulfinyl-2-(4-fluoro­phenyl)-1-benzofuran

نویسندگان

  • Hong Dae Choi
  • Pil Ja Seo
  • Byeng Wha Son
  • Uk Lee
چکیده

In the title compound, C(16)H(12)BrFO(2)S, the 4-fluoro-phenyl ring is rotated out of the benzofuran plane, as indicated by the dihedral angle of 5.94 (5)°. The crystal structure exhibits aromatic π-π inter-actions between the benzene ring and the 4-fluoro-phenyl ring of an adjacent mol-ecule [centroid-centroid distance = 3.632 (2) Å], and a Br⋯O halogen bond with a Br⋯O distance of 3.101 (1) Å.

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منابع مشابه

5-Bromo-3-ethyl­sulfinyl-2-(4-fluoro­phen­yl)-7-methyl-1-benzofuran

In the title compound, C(17)H(14)BrFO(2)S, the 4-fluoro-phenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 7.60 (4)°. The crystal structure is stabilized by a Br⋯O halogen-bonding inter-action [3.048 (1) Å].

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5-Bromo-2-(4-chloro­phen­yl)-3-ethyl­sulfinyl-7-methyl-1-benzofuran

In the title compound, C(17)H(14)BrClO(2)S, the 4-chloro-phenyl ring makes a dihedral angle of 13.42 (4)° with the mean plane of the benzofuran ring. In the crystal, pairs of inter-molecular Br⋯O contacts [3.125 (1) Å] link the mol-ecules into centrosymmetric dimers, which are further linked via inter-molecular C-H⋯O hydrogen bonds.

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3-Ethyl­sulfinyl-2-(4-fluoro­phen­yl)-5-iodo-7-methyl-1-benzofuran

In the title compound, C(17)H(14)FIO(2)S, the 4-fluoro-phenyl ring is rotated out of the benzofuran plane, as indicated by the dihedral angle of 15.60 (6)°. The crystal structure exhibits an I⋯O inter-action [3.052 (2) Å].

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5-Chloro-3-ethyl­sulfinyl-2-(4-fluoro­phen­yl)-7-methyl-1-benzofuran

In the title compound, C(17)H(14)ClFO(2)S, the 4-fluoro-phenyl ring is rotated slightly out of the benzofuran plane, as indicated by the dihedral angle of 8.32 (5)°. The crystal structure features a short Cl⋯O contact [3.092 (1) Å].

متن کامل

5-Chloro-3-ethyl­sulfinyl-2-(4-fluoro­phen­yl)-1-benzofuran

In the title compound, C(16)H(12)ClFO(2)S, the 4-fluoro-phenyl ring is rotated out of the benzofuran plane, as indicated by the dihedral angle of 6.96 (5)°. The crystal structure exhibits a Cl⋯O inter-action with a Cl⋯O distance of 3.163 (1) Å.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010